Expanding Beyond the Micropore: Active-Site Engineering in Hierarchical Architectures for Beckmann Rearrangement
نویسندگان
چکیده
منابع مشابه
Cyclopropenium ion catalysed Beckmann rearrangement.
1-Chloro-2,3-diphenylcyclopropenium ion was found to be a very efficient organocatalyst (3 mol% loading) for liquid phase Beckmann rearrangement of various ketoximes to the corresponding amides/lactams within 2 h in acetonitrile at reflux temperature. This is the first example of the application of the cyclopropenium ion as a catalyst, which opens up a new aspect of the synthetic utility of aro...
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ژورنال
عنوان ژورنال: ACS Catalysis
سال: 2015
ISSN: 2155-5435,2155-5435
DOI: 10.1021/acscatal.5b01595